Polyhydroxyalkanoates and Other Biopolymers

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Isolation and recovery of microbial polyhydroxyalkanoates

The deleterious environmental impacts caused by plastic wastes have attracted worldwide concern. The biobased and biodegradable polyhydroxyalkanoate (PHA) appears to be one of the potential candidates to replace some conventional plastics. However, high production cost of PHAs has limited their market penetration. The major cost absorbing factors are the upstream fermentation processes and the ...

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Keratin Protein-Catalyzed Nitroaldol (Henry) Reaction and Comparison with Other Biopolymers.

Here we describe a preliminary investigation on the ability of natural keratin to catalyze the nitroaldol (Henry) reaction between aldehydes and nitroalkanes. Both aromatic and heteroaromatic aldehydes bearing strong or moderate electron-withdrawing groups were converted into the corresponding β-nitroalcohol products in both DMSO and in water in the presence of tetrabutylammonium bromide (TBAB)...

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ژورنال

عنوان ژورنال: Biomacromolecules

سال: 2019

ISSN: 1525-7797,1526-4602

DOI: 10.1021/acs.biomac.9b01044